Rolling Stones star Mick Jagger had an affair with actress Angelina Jolie when he was still married to ex-wife Jerry Hall, it's been claimed.

A new book, syndicated in today's Sun newspaper, claims the pair struck up a relationship after Jolie appeared in the band's video for 'Anybody Seen My Baby?' in 1997.

They also had another affair in 2003, according to book, which claims to lift the lid on Jolie's life up to and including her relationship with current boyfriend Brad Pitt.

Jagger spent nine years married to Hall – his second wife – after the couple wed in Indonesia in 1990.

The singer, who is currently on hiatus from the Rolling Stones, has been dating fashion designer L'Wren Scott since 2001.

Neither Jagger nor Hall's agents would comment on author Jenny Paul's allegations, according to the newspaper.

(by Jason Gregory)